Aromatic antimony compounds. Transition metal complexes of 2,5-dimethylstibacyclopentadienyl
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چکیده
منابع مشابه
Metal complexes of unsaturated polycarbonyl compounds derived from benzoyl acetone and aromatic aldehydes
Condensation of aromatic aldehydes with benzoyl acetone under specified conditions yieldedtwo series of polycarbonyl compounds in which the keto group is attached to olefinic linkage.Spectral and analytical data revealed the formation of an unsaturated triketone from pyridine-3-carbaldehyde and unsaturated diketone from furfural, salicylaldehyde and 2-hydroxynaphthaldehyde. Analytical, IR, 1H N...
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The group of macrocyclic tetrapyrrolic ligands which includes the porphins, chlorins and corrins, occur in several biologicafly important molecules in the form of metal complexes. Intermediate in structure between the porphins and the corrins are the corroles and the 1 -monosubstituted-, and 1,1 9-disubstituted tetradehydrocorrins. Syntheses and reactions of metal, particularly nickel, complexe...
متن کاملmetal complexes of unsaturated polycarbonyl compounds derived from benzoyl acetone and aromatic aldehydes
condensation of aromatic aldehydes with benzoyl acetone under specified conditions yieldedtwo series of polycarbonyl compounds in which the keto group is attached to olefinic linkage.spectral and analytical data revealed the formation of an unsaturated triketone from pyridine-3-carbaldehyde and unsaturated diketone from furfural, salicylaldehyde and 2-hydroxynaphthaldehyde. analytical, ir, 1h n...
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A wide range of transition metal imido (TMI) complexes is studied using ab initio molecular orbital (MO) calculations. The main computational point of interest is the further testing of effective core potentials (ECPs) and valence basis sets to allow for the accurate calculation of properties for reasonably sized transition metal complexes. On the chemical side, several results from the study a...
متن کاملSn(IV) Compounds Interaction with Metal-Schiff Base Complexes
The formation constants and Gibbs free energy for the interaction of RnSnClm (n = m = 2, R = Me, Ph, n-Bu or n = 4, m = 0, R = Ph) compounds as acceptors, with ML complexes (H2L = N,N'-bis(salicylidene)-2-aminobenzylamine (salabza-H2) and its derivatives, M = Mn2+ or Zn2+), as donors in N,N'-dimethylformamide (DMF) as solvent were studied. These parameters were measured by using UV-vis spectrop...
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ژورنال
عنوان ژورنال: Journal of Organometallic Chemistry
سال: 1980
ISSN: 0022-328X
DOI: 10.1016/s0022-328x(00)81877-x